• 文献标题:   Facile Synthesis and Enhanced Electrochemical Performances of Hierarchical ZnFe2O4-Graphene Hybrid as an Anode Material for Li-Ion Batteries
  • 文献类型:   Article
  • 作  者:   SUN LM, HAN SB, LIU YT, CHEN DF, HU ZB, LIU XF
  • 作者关键词:   lithium ion battery, anode, znfe2o4, hierarchical, graphene
  • 出版物名称:   JOURNAL OF NANOSCIENCE NANOTECHNOLOGY
  • ISSN:   1533-4880 EI 1533-4899
  • 通讯作者地址:   China Inst Atom Energy
  • 被引频次:   2
  • DOI:   10.1166/jnn.2017.12831
  • 出版年:   2017

▎ 摘  要

ZnFe2O4 nanosheets with some nanopores have been synthesized for the first time by a facile co-precipitation method. Subsequently, the ZnFe2O4-graphene hybrid (RGO-ZnFe2O4) with a hierarchical structure are fabricated by in situ chemical reduction of graphene oxide (GO). X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) are employed to characterize the hierarchical structure and morphology. The cycling performance and rate capability of RGO-ZnFe2O4 are largely enhanced. After 50 cycles, the reversible capacity at a current density of 100 mA g(-1) is kept at 871.2 mAh g(-1), which is about 5 times of bare ZnFe2O4. At a current density of 1000 mA g(-1) the capacity of RGO-ZnFe2O4 is about 455.5 mAh g(-1) but the capacity of bare ZnFe2O4 is only about 125 mAh g(-1). The high cyclability and high-rate capability of RGO-ZnFe2O4 can be attributed to the synergetic effect of the conductive graphene and the hierarchical architecture structure.