• 文献标题:   Facile fabrication of Fe3O4 octahedra with bimodal conductive network of nanoporous Cu and graphene nanosheets for high-performance anode in Li-ion batteries
  • 文献类型:   Article
  • 作  者:   HAO Q, YE JJ, XU CX
  • 作者关键词:   fe3o4, graphene, nanocomposite, dealloying, liion batterie
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   6
  • DOI:   10.1016/j.jallcom.2017.08.139
  • 出版年:   2017

▎ 摘  要

Fe3O4/Cu@ graphene (Fe3O4/Cu@G) nanocomposite is prepared through a facile fabrication of Fe3O4/Cu precursor by dealloying FeCuAl alloy followed by the reduction of coassembled aggregates of Fe3O4/Cu and graphene oxide. The obtained Fe3O4 octahedra are well enwrapped in nanoporous Cu network and graphene nanosheets. Benefitting from the bimodal conductive network of Cu and graphene, the Fe3O4/Cu@G composite exhibits much higher specific capacity and dramatically enhanced cycling stability compared with the pure Fe3O4 octahedra, Fe3O4/Cu, and Fe3O4@G composite. Moreover, the Fe3O4/Cu@G electrode shows satisfactory cycling reversibility even at a current rate up to 2000 mA g(-1) for 800 cycles. Owing to the superiorities of high electrochemical performances and easy preparation, the Fe3O4/Cu@G composite shows encouraging application potential to be an advanced anode material for lithium storage. (C) 2017 Elsevier B.V. All rights reserved.