• 文献标题:   Polyaniline nanofibers-graphene oxide nanoplatelets composite thin film electrodes for electrochemical capacitors
  • 文献类型:   Article
  • 作  者:   KHALID M, TUMELERO MA, ZOLDAN VC, CID CCP, FRANCESCHINI DF, TIMM RA, KUBOTA LT, MOSHKALEV SA, PASA AA
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Fed Santa Catarina
  • 被引频次:   13
  • DOI:   10.1039/c4ra06145d
  • 出版年:   2014

▎ 摘  要

Composite thin films of polyaniline (PANI) nanofibers and graphene oxide (GO) nanoplatelets are synthesized through a simple electrodeposition process for electrochemical capacitors. The morphology and structure of the materials are investigated by field emission scanning electron microscopy, transmission electron microscopy, current sensing atomic force microscopy, X-ray photoelectron spectroscopy, Fourier transforms infrared spectroscopy, X-ray diffraction, and ultraviolet-visible spectroscopy. In the process of electrodeposition, the electrostatic interactions between the oxygen-functionalized graphene and aniline monomers at an electrolyte interface assisted the co-deposition of PANI nanofibers and GO nanoplatelets. These thin films have an excellent effect on the electrochemical properties with an electrochemical capacitance of 662 F g(-1) at a low current density of 0.025 mA cm(-2) with simultaneous high energy density (64.5 W h kg(-1)) and high power density (1159 W kg(-1)). The excellent electrochemical performance of the films is attributed to the unique structure of the material, showing synergy between PANI nanofibers and GO nanoplatelets.