▎ 摘　　要

The concept of a core shell metallic structures, with a few atomic layers of the "shell" metal delineated from the "core" metal with atomic sharpness opens the door to a multitude of surface-driven materials properties that can be tuned. However, in practice, such architectures are difficult to retain due to the entropic cost of a segregated near-surface architecture, and the core and surface atoms inevitably mix through interdiffusion over time. We present here a systematic study of interdiffusion in a Pt on Au core shell architecture and the role of an interrupting single layer of graphene sandwiched between them. The physical and chemical structure of the (near)surface is probed via mean-free-path tuned X-ray photoelectron spectroscopy, high-resolution transmission electron microscopy (HRTEM), and electrochemistry (the oxygen reduction reaction, ORR). We find that at operating temperatures above 100 degrees C, there is potential for interdiffusion to occur between the primary and support metals of the core shell catalyst system, which can diminish the catalyst activity toward ORR The introduction of a single-layer graphene, as an interface between the core and shell metal layers, acts as a barrier that prevents unwanted surface alloying between the layered metals. HRTEM imaging shows that fully wetted Pt monolayers can be grown on a graphene template, allowing a high level of surface utilization of the catalyst material. We present how the use of graphene as a barrier to diffusion mitigates the loss of surface catalytic sites, showing much improved retention of Pt monolayer surface at elevated temperatures.