• 文献标题:   One-step synthesis of Ni3S2 nanoparticles wrapped with in situ generated nitrogen-self-doped graphene sheets with highly improved electrochemical properties in Li-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHU JL, LI YY, KANG S, WEI XL, SHEN PK
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Xiantan Univ
  • 被引频次:   93
  • DOI:   10.1039/c3ta14562j
  • 出版年:   2014

▎ 摘  要

A facile strategy has been developed to fabricate Ni3S2 nanoparticles wrapped with in situ generated N-doped graphene sheets (Ni3S2@N-G). In this strategy, the nitrogen and sulfur-containing resin is introduced as a sulfur source to form the Ni3S2 nanoparticles and to provide a source of nitrogen and carbon to grow a coating of N-doped graphene sheets on their surface. As an anode material in lithium-ion batteries (LIBs), Ni3S2@N-G exhibits a highly improved reversible capacity, as well as an excellent cycling performance and rate performance. It delivers a discharge capacity of up to 809 mA h g(-1) in the 150th cycle. With the successful synthesis of Ni3S2@N-G as a starting point, this facile strategy can be used to synthesize other metal sulfides/graphene sheets nanocomposites and will immensely extend its applications.