• 文献标题:   Bottom-up synthesis of graphene/polyaniline nanocomposites for flexible and transparent energy storage devices
  • 文献类型:   Article
  • 作  者:   SOUZA VHR, OLIVEIRA MM, ZARBIN AJG
  • 作者关键词:   chemical synthesis of graphene, supercapacitor, polymeric nanocomposite, liquidliquid interface, thin film
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Fed Univ Parana UFPR
  • 被引频次:   16
  • DOI:   10.1016/j.jpowsour.2017.02.064
  • 出版年:   2017

▎ 摘  要

An innovative, single-pot synthesis for chemically producing graphene/polyaniline nanocomposites is presented. The method, which is based on chemical reactions at liquid-liquid interfaces, begins with benzene and aniline and ultimately yields nanocomposites as thin films of polyaniline mixed with graphene. These films self-assembled at the water-benzene interface are easily transferable to any kind of ordinary substrates, plastics included. Nanocomposites prepared with different polymer/graphene ratios show differentiated structures and morphologies, resulting in excellent pseudocapacitive behaviors (specific capacitance of 267.2 F cm(-3)). The construction of all-solid, transparent, and flexible supercapacitor device from this nanocomposite is also presented. (C) 2017 Elsevier B.V. All rights reserved.