• 文献标题:   Mild solution synthesis of graphene loaded with LiFePO4-C nanoplatelets for high performance lithium ion batteries
  • 文献类型:   Article
  • 作  者:   LIU MC, ZHAO Y, GAO S, WANG Y, DUAN YX, HAN X, DONG Q
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Beihang Univ
  • 被引频次:   12
  • DOI:   10.1039/c4nj01485e
  • 出版年:   2015

▎ 摘  要

To reduce the reaction time, electric energy consumption and the need for high pressure as well as unsafe conditions, we developed an easy and efficient method for the synthesis of a LiFePO4-graphene-C composite. The cathode material was fabricated in situ in an open system by microwave-assisted solvent treatment. The disc-shaped LiFePO4 nanoparticles were 50-100 nm in size and well dispersed on the surface of the graphene. The cyclic voltammograms, charge-discharge profiles and electrochemical impedance measurements indicated that the electrochemical performances of the LiFePO4-graphene-C were better than those of LiFePO4-graphene and LiFePO4-C composites. The LiFePO4-graphene-C cathode delivered a capacity of 160.1 mA h g(-1) at 0.1 C rate and showed a decay rate of no more than 0.09% per cycle. The effect of graphene on the structure and performance of the composites was investigated.