• 文献标题:   Graphene-based strontium niobate-zinc oxide heterojunction photocatalyst for effective reduction of hexavalent chromium
  • 文献类型:   Article
  • 作  者:   RAJA A, SON N, KANG M
  • 作者关键词:   shows suppressed charge, hydrothermal technique, chromium vi reduction, photocatalytic reduction, strontium niobatezinc oxide
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.chemosphere.2023.138781 EA APR 2023
  • 出版年:   2023

▎ 摘  要

A hydrothermal technique was employed to synthesize a Sr2Nb2O7-rGO-ZnO (SNRZ) ternary nanocatalyst, in which ZnO and Sr2Nb2O7 were deposited on reduced graphene oxide (rGO) sheets. The surface morphologies, optical properties, and chemical states, of the photocatalysts were characterized to understand their properties. The SNRZ ternary photocatalyst was superior over the reduction of Cr (VI) to harmless Cr (III) compared to the efficiencies obtained using bare, binary, and composite catalysts. The effects of various parameters, including the solution pH and weight ratio, on the photocatalytic reduction of Cr (VI) were investigated. The highest photo -catalytic reduction performance (97.6%) was achieved at pH 4 and a reaction time of 70 min. Photoluminescence emission measurements were used to confirm efficient charge migration and separation across the SNRZ, which improved the reduction of Cr (VI). A feasible reduction mechanism for the SNRZ photocatalyst is proposed. This study presents an effective, inexpensive, non-toxic, and stable catalyst, for the reduction of Cr (VI) to Cr (III) using SNRZ ternary nanocatalysts.