• 文献标题:   One-step preparation of nitrogen-doped graphene nanosheets for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   GAO BF, ZHOU HT, YANG JH
  • 作者关键词:   anisotropic geometry, koh, oriented activation, gn, ionic liquid
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   9
  • DOI:   10.1016/j.apsusc.2017.03.015
  • 出版年:   2017

▎ 摘  要

Graphene nanosheets (GNs) have been successfully synthesized by one-step carbonization and simultaneous chemical activation of polyaniline (PANI) nanofibers, with large surface area (1759.5 m(2) g(-1)), high pore volume (1.16 cm(3) g(-1)) and a mesopore rich structure (volume in micropore/total ratio, 2.16%). The vital (NDs) become entrapped within a carbon lattice (to form GNs). GNs could be used as an outstanding electrode material for supercapacitors in EMIMBF4 with high cycling stability (more than 73% retention of the initial capacitance after 10,000 cycles). The symmetric supercapacitor has an excellent energy density of 170.2 Wh kg(-1) (25 degrees C) at 0.5 A g(-1), with an operating cell voltage of 4.0 V. Meanwhile, oriented activation with polymers of anisotropic geometry might be regarded as a novel process to prepare GNs. (C) 2017 Elsevier B.V. All rights reserved.