• 文献标题:   Ni-Co Double Hydroxide Grown on Graphene Oxide for Enhancing Lithium Ion Storage
  • 文献类型:   Article
  • 作  者:   SONG F, ZHANG R, ZHANG XY, QIN JQ, LIU RP
  • 作者关键词:  
  • 出版物名称:   ENERGY FUELS
  • ISSN:   0887-0624 EI 1520-5029
  • 通讯作者地址:   Yanshan Univ
  • 被引频次:   0
  • DOI:   10.1021/acs.energyfuels.0c01637
  • 出版年:   2020

▎ 摘  要

It still remains a major challenge to maintain the excellent lithium ion-storage performance of layered double hydroxide (LDH) for lithium ion battery anodes at high current density and long cycle times. Herein, a hybrid material was developed by anchoring Co/Ni/LDH (CoNi-LDH) on the surface of graphene oxide (GO) to obtain good structural stability. During the growth process, the beta phase with a low value (4.6 angstrom) of interlayer spacing was converted to the alpha phase with a high value (8.1 angstrom) of interlayer spacing and the sheet became thinner than that of CoNi-LDH alone. X-ray photoelectron spectroscopy (XPS) results demonstrate the formation of the C=O chemical bond between the ultra thin CoNi-LDH and GO, which increased the structural stability and effectively reduced the charge-transfer impedance. As expected, the long-life cycling stability with a specific capacity of 440 mAh/g for 500 cycles was achieved at a high current density of 5 A/g, indicating that the structural degradation of CoNi-LDH was successfully suppressed by the introduction of GO.