• 文献标题:   Microwave-assisted synthesis of hydroxyl modified fluorinated graphene with high fluorine content and its high load-bearing capacity as water lubricant additive for ceramic/steel contact
  • 文献类型:   Article
  • 作  者:   MA LM, LI ZP, JIA WH, HOU KM, WANG JQ, YANG SR
  • 作者关键词:   microwaveassisted, water dispersible, fluorinated graphene, tribology
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:  
  • 被引频次:   8
  • DOI:   10.1016/j.colsurfa.2020.125931
  • 出版年:   2021

▎ 摘  要

The fluorinated graphene (FG) has been reported in diverse applications for its unique chemical and physical properties, resulting from the 2D carbon-skeleton and decorated C - F bonds. How to substitute the FG's fluorine atom with other active functional groups and retain its fluorine content is still a challenge. In this work, a microwave-assisted liquid-phase synthetic route was introduced to obtain hydroxyl modified fluorinated graphene (HOFG) with high fluorine content. The as-prepared product exhibits excellent water dispersibility with far less fluorine loss than previously reported methods. It is found that the HOFG's fluorine/oxygen (F/O) ratio plays a crucial role in the water dispersibility and lubricating property. The as-prepared HOFG exhibits excellent dispersibility at a high F/O ratio (35). Used as the water lubrication additive for ceramic-steel pair, the as-prepared HOFG significantly improves water's load-bearing capacity from 250N to 600N. The friction-reduction and anti-wear ability of water are also improved with the addition of the HOFG samples. Compared with pure water, the aquous dispersion of HOFG-40M at a concentration of 1.5 mg/mL shows the best lubricating property with a nearly 20 % reduction of friction coefficient and a 30 % decrease of wear.