• 文献标题:   High Capacitive Storage Performance of Sulfur and Nitrogen Codoped Mesoporous Graphene
  • 文献类型:   Article
  • 作  者:   MA XL, GAO DW
  • 作者关键词:   doping, electrochemistry, graphene, mesoporous material, supercapacitor
  • 出版物名称:   CHEMSUSCHEM
  • ISSN:   1864-5631 EI 1864-564X
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   11
  • DOI:   10.1002/cssc.201702457
  • 出版年:   2018

▎ 摘  要

Mesoporous graphene is synthesized based on the chemical vapor deposition methodology by using heavy MgO flakes as substrates in a fluidized-bed reactor. Subsequently, sulfur and nitrogen coincorporation into graphene frameworks is realized by the reaction between carbon atoms and thiourea molecules. The as-obtained sulfur and nitrogen codoped mesoporous graphene (SNMG) exhibits remarkable capacitive energy-storage behavior, as a result of well-developed pore channels, in terms of that in a symmetric supercapacitor and lithium-ion hybrid capacitor (LIHC). The ultrahigh durability of the SNMG/SNMG symmetric supercapacitor is demonstrated by long-term cycling, for which no capacitance decay is found after 20000 cycles. A LIHC constructed from commercial Li4Ti5O12 (LTO) as the anode and SNMG as the cathode is capable of delivering much enhanced lithium-storage ability and better rate capability than that of activated carbon (AC)/LTO LIHC. Moreover, SNMG/LTO LIHC exhibits maximum energy and power densities of 86.2 Wh kg(-1) and 7443 W kg(-1) and maintains 87% capacitance retention after 2000 cycles.