• 文献标题:   MoCl5 intercalation doping and oxygen passivation of submicrometer-sized multilayer graphene
  • 文献类型:   Article
  • 作  者:   MIYAZAKI H, MATSUMOTO R, KATAGIRI M, YOSHIDA T, UENO K, SAKAI T, KAJITA A
  • 作者关键词:  
  • 出版物名称:   JAPANESE JOURNAL OF APPLIED PHYSICS
  • ISSN:   0021-4922 EI 1347-4065
  • 通讯作者地址:   Toshiba Co Ltd
  • 被引频次:   5
  • DOI:   10.7567/JJAP.56.04CP02
  • 出版年:   2017

▎ 摘  要

We investigated doping material selection for multilayer graphene (MLG) interconnects and a passivation process to stabilize the doped state. Intercalation doping with Br-2, FeCl3, and MoCl5 was compared in terms of doping ability and robustness against environmental effects, which are exacerbated by miniaturization. We found that MoCl5 was advantageous for miniaturization. We hypothesized that environmental stability would be enhanced by partially oxidizing MoCl5 and avoiding hydrolysis by water vapor in air. To test this, we examined a passivation process by dry oxygen exposure. We verified that the doping effect was improved and that intercalated material (MoCl5) was partially oxidized and confined in the MLG. (C) 2017 The Japan Society of Applied Physics