• 文献标题:   Graphene-encapsulated Li2MnTi3O8 nanoparticles as a high rate anode material for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   YANG L, ZHANG XY, LI Y, HAO F, CHEN HS, YANG M, FANG DN
  • 作者关键词:   li2mnti3o8, lithiumion battery, anode, titanate material, grapheneencapsulated
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   15
  • DOI:   10.1016/j.electacta.2014.12.133
  • 出版年:   2015

▎ 摘  要

Graphene-encapsulated Li2MnTi3O8 nanoparticles were synthesized via a modified sol-gel process using graphene oxide as the template. The prepared Li2MnTi3O8 material has a complex spinel structure in the P4(3)32 space group. The morphology of the graphene-encapsulated Li2MnTi3O8 composite indicates that the Li2MnTi3O8 particles can be uniformly scattered on a graphene substrate, and these particles have a size of 10-20 nm. The electrochemical properties indicate that the graphene-encapsulated Li2MnTi3O8 material possesses a stable reversible discharge capacity of similar to 220mAh g(-1) after 50 cycles at 0.1 C. In addition, the reversible capacity at 2 C improved by 70% after graphene-encapsulation, which indicates the excellent high rate capability. (C) 2014 Elsevier Ltd. All rights reserved.