• 文献标题:   Local Contact Fluorination of Graphene
  • 文献类型:   Article
  • 作  者:   CHILINGAROV NS, SKOKAN EV, KNOT KO AV, ELISEEV AA
  • 作者关键词:   atomic fluorine, graphene, interface, solidphase fluorination, surface diffusion
  • 出版物名称:   CHEMNANOMAT
  • ISSN:   2199-692X
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/cnma.202000668 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

A procedure for solid-phase fluorination of graphene is described that provides fluorine addition at the interfaces of graphene with solid fluorinating reagents. Graphene sheets were formed on a copper substrate (Cu-G) with a specific wave-like microstructure. A solid fluorinating reagent, {Pt2F6-PtF4} solid solution, was layered on a Pt substrate (Pt-F). Thermally activated fluorination is found to be localized to the linear contacts of the Pt-F surface with the "ridges" of the Cu-G waves, leading to alternating stripes of intact and fluorinated graphene. Thus, the use of specifically profiled substrates for the graphene layer and/or the solid-phase fluorinating reagent offers a promising approach to create fluorinated zones of the desired shape and size.