▎ 摘　　要

Novel porous polymer/graphene composite aerogels with a multiple network structure, enhanced compressive properties and high thermal conductivity are first fabricated by adsorbing water vapour, reduction, and freeze-drying procedures. The aerogels are comprised of a copolymer of monomethacrylate terminated poly(dimethylsiloxane) and glycidyl methacrylate (PDMS-PGMA), polydopamine-reduced graphene oxide (PDA-rGO), and poly(3-mercaptopropyl) methylsiloxane (PMMS). PMMS as a crosslinking agent reacts with PDMS-PGMA and PDA-rGO by the thiol-Michael addition click reaction, resulting in the formation of unique multiple networks in the aerogels. An aerogel with a low graphene loading (2 wt%) exhibits optimal comprehensive performance, i.e. a high thermal conductivity (0.816 W m(-1) K-1), high compressive stress at 50% compression ratio (3.4 MPa) and good oil-adsorption capacities. These outstanding properties of aerogels are attributed to the multiple networks and the interconnected PDA-rGO skeleton. The aerogels have potential applications in heat radiating elements, oil/water separators and high performance materials.