• 文献标题:   Antistatic PVC-graphene Composite through Plasticizer-mediated Exfoliation of Graphite
  • 文献类型:   Article
  • 作  者:   WEI ZB, ZHAO Y, WANG C, KUGA S, HUANG Y, WU M
  • 作者关键词:   antistatic composite, poly vinyl chloride, graphene, mechanical exfoliation, electrical property
  • 出版物名称:   CHINESE JOURNAL OF POLYMER SCIENCE
  • ISSN:   0256-7679 EI 1439-6203
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   2
  • DOI:   10.1007/s10118-018-2160-5
  • 出版年:   2018

▎ 摘  要

Multilayer graphene was prepared by mechanical exfoliation of natural graphite with dioctyl phthalate (DOP) as milling medium without solvent. The obtained mixture could be directly mixed with poly(vinyl chloride) (PVC) for melt-forming, with DOP acting as plasticizer and graphene acting as conductive filler for antistatic performance. The composite showed surface resistance of 2.5 x 10(6) / at 1 wt% carbon additive, significantly lower than approx. 7 wt% of raw graphite required for achieving the same level. This value is low enough for practical antistatic criterion of 3 x 10(8) /. The effect of filler addition on mechanical performance was minimal, or even beneficial for the milled carbon in contrast to the case of raw graphite.