▎ 摘　　要

A novel one-step electrochemical composite polymerization strategy was first proposed to prepare unique polypyrrole/reduced graphene oxide/carbon nanotubes (PPy/F-RGO/CNTs) ternary composites, where F-RGO, ChM, and PPy were electrodeposited simultaneously to construct a three-dimensional (3D) highly porous film electrode. Such ternary composite film electrode exhibits a high specific capacitance of 300 F g(-1) at 1 A g(-1) as well as a remarkable cycling stability at high rates, which is related to its unique nanostructure and high electrical conductivity. F-RGO and CNTs act as an electron-transporting backbone of a 3-D porous nanostructure, leaving adequate working space for facile electrolyte penetration and better faradaic utilization of the electro-active PPy. Furthermore, the straightforward approach proposed here can be readily extended to prepare other composite film electrodes with good electrochemical performance for energy storage. (C) 2011 Elsevier Ltd. All rights reserved.