• 文献标题:   FACILE PREPARATION AND CHARACTERIZATION OF GRAPHENE NANOSHEET/POLYANILINE NANOFIBER THERMOELECTRIC COMPOSITES
  • 文献类型:   Article
  • 作  者:   DU Y, CAI KF, SHEN S
  • 作者关键词:   graphene nanosheet, polyaniline nanofiber, thermoelectric propertie, composite
  • 出版物名称:   FUNCTIONAL MATERIALS LETTERS
  • ISSN:   1793-6047 EI 1793-7213
  • 通讯作者地址:   Tongji Univ
  • 被引频次:   9
  • DOI:   10.1142/S179360471340002X
  • 出版年:   2013

▎ 摘  要

Graphene nanosheet (GNs)/polyaniline (PANI) nanofiber composites were prepared by oxidative polymerization of aniline in a GNs dispersed 1 mol/L HCl solution. The phase composition of the composites was analyzed by Fourier Transform Infrared Spectroscopy and X-ray Diffraction. The thermoelectric properties of the composite powders, after cold pressing into pellets, were measured at room temperature. As the content of GNs increased from 0 to 40 wt.%, the electrical conductivity and Seebeck coefficient of the composite pellets increased simultaneously; especially the electrical conductivity increased dramatically from 15.4 to 120.1 S/cm. The highest power factor (similar to 394.4 x 10(-8) Wm(-1)K(-2)) was obtained from the 40 wt.% GNs/PANI composite sample, which is similar to 200 times as high as that of HCl-doped PANI.