• 文献标题:   High performance asymmetric supercapacitor device based on lanthanum doped nickel-tin oxide/reduced graphene oxide composite
  • 文献类型:   Article
  • 作  者:   PAUL A, GHOSH S, KOLYA H, KANG CW, MURMU NC, KUILA T
  • 作者关键词:   nickeltin oxide, la doping, oxygen vacancy, potential window, asymmetric supercapacitor
  • 出版物名称:   JOURNAL OF ENERGY STORAGE
  • ISSN:   2352-152X EI 2352-1538
  • 通讯作者地址:  
  • 被引频次:   3
  • DOI:   10.1016/j.est.2022.105526
  • 出版年:   2022

▎ 摘  要

Doping is the most promising approach to improve the electrochemical performance of metal oxide-based supercapacitor. Rare-earth element doping is helpful to improve the electrochemical performance of metal oxides due to the presence of unique 4f electronic configuration. Herein, Lanthanum (La) doped Nickel-tin oxide/reduced graphene oxide (LNSRG) composite was successfully prepared via one-step hydrothermal method. The optimized LNSRG 2 composite exhibited similar to 1238 F g(-1) specific capacitance at 3 A g(-1) current density using 6 M KOH as electrolyte. The effect of electrolyte's pH on the electrochemical performances was investigated using various electrolytes. The asymmetric supercapacitor (ASC) device fabricated with LNSRG 2 as positive electrode material and sonochemically reduced graphene oxide (SRGO) as negative electrode material exhibited energy density of similar to 38 W h kg(-1) at a power density of similar to 870 W kg(-1) in the potential window of similar to 1.6 V using 1 M Na2SO4 as electrolyte. The ASC device retained similar to 75 % of its initial capacitance after 10,000 continuous charge-discharge cycles at 15 A g(-1) current density. Two ASC devices connected in series was capable of powering a 1.8 V red LED light.