• 文献标题:   Large scale production of nanoporous graphene sheets and their application in lithium ion battery
  • 文献类型:   Article
  • 作  者:   ZHANG JN, GUO BH, YANG YQ, SHEN WZ, WANG YM, ZHOU XJ, WU HX, GUO SW
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Shanghai Jiao Tong Univ
  • 被引频次:   27
  • DOI:   10.1016/j.carbon.2014.12.039
  • 出版年:   2015

▎ 摘  要

Nanoporous graphene sheets were generated through a simple thermal annealing procedure using composites of ferrocene nanoparticles and graphene oxide sheets as precursors in a large scale. The morphology, composition, and formation mechanism of the as-obtained nanoporous graphene sheets were studied complementarily with scanning electron microscopy, transmission electron microscopy, X-ray powder diffraction, and other spectroscopy techniques. We found that the density of nanopores on the graphene sheet was determined by the surface distribution of oxygen-containing groups on the original graphene oxide sheets. The coin cells using nanoporous graphene sheets as anode materials showed higher specific lithium ion storage capacity, better discharge/charge rate capability and higher cycling stability when compared to the coin cells with graphene or chemically reduced graphene sheets as anodes. (C) 2014 Elsevier Ltd. All rights reserved.