• 文献标题:   Effects of disorder on the optical properties of CVD grown polycrystalline graphene
  • 文献类型:   Article
  • 作  者:   PODILA R, ANAND B, SPEAR JT, PUNEET P, PHILIP R, SAI SSS, RAO AM
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Clemson Univ
  • 被引频次:   27
  • DOI:   10.1039/c2nr11206j
  • 出版年:   2012

▎ 摘  要

We explore the effects of crystallite size (L-a) on the linear and non-linear optical properties of chemical vapor deposition grown polycrystalline graphene. The pi-plasmon resonance present at similar to 4.75 eV (similar to 260 nm) in the optical absorption spectrum of graphene follows the empirical relationship lambda(pi) 250.5 nm + 89.5 nm(2)/L-a, where lambda(pi) represents the pi-plasmon wavelength. Furthermore, our Z-scan studies reveal that the crystallite size significantly changes the saturation intensity in CVD grown graphene. Notably, in comparison to epitaxial graphene layers grown on SiC wafers which exhibit a photogenerated carrier lifetime of few picoseconds, we find that the photogenerated carriers in our CVD grown graphene can exhibit lifetimes as long as nanoseconds.