• 文献标题:   LiVPO4F@C particles anchored on boron-doped graphene sheets with outstanding Li+ storage performance for high-voltage Li-ion battery
  • 文献类型:   Article
  • 作  者:   YANG YA, CHEN C, SUN H
  • 作者关键词:   livpo4f@c cathode, borondoped graphene, energy storage, rate property
  • 出版物名称:   SOLID STATE IONICS
  • ISSN:   0167-2738 EI 1872-7689
  • 通讯作者地址:   Tianjin Univ Commerce
  • 被引频次:   6
  • DOI:   10.1016/j.ssi.2018.12.010
  • 出版年:   2019

▎ 摘  要

LiVPO4F has been suggested as an excellent electrode for Li-ion battery due to its various advantages. However, the LiVPO4F-based materials reported so far showed poor rate property and required further improvement. Herein, we describe a simple method to synthesize the boron-doped graphene-decorated LiVPO4F@C (BG-LiVPO4F@C) composite for the first time. This designed nanostructure can provide short diffusion distance for Li+ and offer enhanced electronic conductivity for the transport of electron, leading to superior Li+ storage performance. The obtained electrode delivers high capacity of 125.2 mAh g(-1) at 10C. Besides, it exhibits excellent cyclic stability with a high capacity retention of about 92.5% after 300 cycles at 20C. Thus, the as synthesized BG-LiVPO4F@C cathode is a promising candidate for Li-ion battery.