• 文献标题:   Excellent cycling stability with high SnO2 loading on a three-dimensional graphene network for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG M, SUN ZH, ZHANG TF, SUI D, MA YF, CHEN YS
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Nankai Univ
  • 被引频次:   49
  • DOI:   10.1016/j.carbon.2016.02.032
  • 出版年:   2016

▎ 摘  要

Carbon materials, including pyrolytic carbon and nanocarbon, especially graphene, have been reported to be introduced in the SnO2-based anodes to decrease the capacity decay during cycling, but the capacity fading was not effectively suppressed. Herein, we report a three-dimensional cross-linked graphene material as the template to load electrochemically active material SnO2. A 3D composite of graphene and SnO2 was obtained with a relatively higher SnO2 loading of 89.51 wt%. The material shows excellent cycling stability with high reversible specific capacity (97% capacity retention, ca. 1096 mA h g(-1) after 150 cycles at 1 A g(-1) with 95% capacity retention, and ca. 1073 mA h g(-1) after 500 cycles at 1 A g(-1)). Furthermore, its specific capacity remains at around 610 mA h g(-1) at a high current density of 5 A g(-1) (fully charged in similar to 15 min). (C) 2016 Elsevier Ltd. All rights reserved.