• 文献标题:   An electrochemical sensor for the determination of bisphenol A using glassy carbon electrode modified with reduced graphene oxide-silver/poly-L-lysine nanocomposites
  • 文献类型:   Article
  • 作  者:   LI YH, WANG HQ, YAN B, ZHANG HY
  • 作者关键词:   reduced graphene oxide rgo, nanocomposite, electrochemical sensor, bisphenol a, differential pulse voltammetry
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   14
  • DOI:   10.1016/j.jelechem.2017.10.022
  • 出版年:   2017

▎ 摘  要

Bisphenol A (BPA) is an effective endocrine-disrupting compound (EDC) that causes adverse effects on human health and environment. Therefore, it is indispensable to construct efficacious methods for evaluating the level of BPA to enhance the quality of life. In this study, a facile electrochemical sensor based on reduced graphene oxide-silver/poly-L-lysine nanocomposites (RGO-Ag/PLL) modified glassy carbon electrode (GCE) is proposed for the detection of BPA. The synthesized RGO-Ag/PLL nanocomposites displays high electrocatalytic activity towards the electrochemical oxidation of BPA. Differential pulse voltammetry (DPV) is used as an analytical method for the quantitative determination of BPA, and the fabricated electrochemical sensor exhibits a linear response to BPA in the range of 1-80 mu M with the limit of detection (LOD) of 0.54 mu M at a signal-to-noise ratio of 3. Additionally, the developed RGO-Ag/PLL/GCE sensor is applied to detect the BPA in drinking water, and obtains satisfactory results.