• 文献标题:   Characterization of the Electrochemical Properties of Nitrogen-Doped Graphene
  • 文献类型:   Article
  • 作  者:   SONG JY, WANG SL, WANG XL, WANG K
  • 作者关键词:   graphene oxide, nitrogendoped graphene, melamine, microwave, energy storage
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.20964/2021.01.35
  • 出版年:   2021

▎ 摘  要

In recent years, graphene has attracted extensive attention in many fields. A nitrogen-doped graphene sheet was synthesized using a solid microwave-mediated method. An experimental electrode was thereafter prepared using nitrogen-doped graphene sheets (NGS), and the physical and electrochemical properties of nitrogen-doped graphene sheets were studied. A three-electrode supercapacitor test system with the experimental electrode also serving as one of the electrodes was built to conduct constant current charge/discharge, cyclic voltammetry, life span, and impedance spectrum tests on the experimental electrode. After 5000 cycles of charging/discharging at a current density of 0.5 A/g, the specific capacitance of the experimental electrode was 208.17 F/g with corresponding capacitance retention of 98.56%; when the current density was increased to 5 A/g, the specific capacitance of the experimental electrode after 5000 cycles of charging/discharging dropped to 157.31 F/g, indicating capacitance retention of 75.57%. The effective series resistance was approximately 0.32 Omega. Owing to the stable properties and high relative spatial surface area of NGS, ions have a good contact rate and charge exchange capacity between the electrode and the electrolyte interface, thereby ensuring a stable supercapacitor capacitance.