• 文献标题:   Hydrothermal synthesis of hydroxyapatite-reduced graphene oxide (1D-2D) hybrids with enhanced selective adsorption properties for methyl orange and hexavalent chromium from aqueous solutions
  • 文献类型:   Article
  • 作  者:   KARTHIKEYAN P, ELANCHEZHIYAN SSD, BANU HAT, FARZANA MH, PARK CM
  • 作者关键词:   mo, cr vi, adsorption, reduced graphene oxide, hydroxyapatite
  • 出版物名称:   CHEMOSPHERE
  • ISSN:   0045-6535 EI 1879-1298
  • 通讯作者地址:  
  • 被引频次:   20
  • DOI:   10.1016/j.chemosphere.2021.130200 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

The presence of organic dye molecules and heavy metal ions in water causes ecological and public health problems. Therefore, remediation of water/wastewater contaminated with organic dye molecules and toxic metal ions is of importance. Herein, a reduced graphene oxide (RGO)ehydroxyapatite (Hat) (1D-2D) hybrid composite was fabricated through a hydrothermal process and applied for the adsorption of methyl orange (MO) and hexavalent chromium (Cr(VI)) from water. The as-fabricated RGO-Hat hybrids were characterized using FTIR, XRD, HR-TEM, SEM, XPS, EDAX, and TGA-DSC analytical techniques. The influencing parameters of adsorption performance, namely solution pH, contact time, and co-interfering ions, were explored to obtain the maximum adsorption capacity of contaminants from the solideliquid interface. Batch studies revealed that MO and Cr(VI) adsorption followed the pseudo-second-order kinetic and the Langmuir isotherm models. The adsorption capacity was 49.14 and 45.24 mg g(-1) for MO and Cr(VI), respectively. The adsorption of such ions over RGO-Hat hybrids was mainly driven by several uptake mechanisms viz, electrostatic force of attraction, pi-pi interactions, and hydrogen bonding. Thus, this study demonstrated that the RGO-Hat hybrid is a potential candidate for the treatment of MO and Cr(VI) from water. (C) 2021 Elsevier Ltd. All rights reserved.