• 文献标题:   Semiconductor Nanocrystals-Reduced Graphene Composites for the Electrochemical Detection of Carbendazim
  • 文献类型:   Article
  • 作  者:   SANTANA PCA, LIMA JBS, SANTANA TBS, SANTOS LFS, MATOS CRS, DA COSTA LP, GIMENEZ IF, SUSSUCHI EM
  • 作者关键词:   quantum dot, reduced graphene oxide, electrochemistry detection, carbendazim pesticide
  • 出版物名称:   JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
  • ISSN:   0103-5053 EI 1678-4790
  • 通讯作者地址:   Univ Fed Sergipe
  • 被引频次:   4
  • DOI:   10.21577/0103-5053.20190026
  • 出版年:   2019

▎ 摘  要

A new nanocomposite based on ZnCdTe semiconductor nanocrystals (NCs) synthesized in situ on reduced graphene oxide (rGO) was obtained. The heterostructure was characterized using UV-Vis emission and absorption spectroscopies, which provided evidences of the growth of the nanocrystals onto the rGO matrix. To evaluate the electrochemical performance, carbon paste electrodes modified with the nanocomposite (QD-rGO/CPE) were prepared, showing high sensitivity in the electroanalytical detection of the pesticide carbendazim. Under optimal operational conditions a calibration curve was constructed with a linear behavior in the range of 9.98 x 10(-8) to 1.18 x 10(-5) mol L-1, with a correlation coefficient of 0.997. The limit of detection (LOD) and the limit of quantification (LOQ) for carbendazim were 9.16 x 10(-8) and 2.78 x 10(-7) mol L-1, respectively. The electrode is successfully applied for the determination of carbendazim in orange juice samples.