• 文献标题:   Electrochemical bisphenol A sensor based on N-doped graphene sheets
  • 文献类型:   Article
  • 作  者:   FAN HX, LI Y, WU D, MA HM, MAO KX, FAN DW, DU B, LI H, WEI Q
  • 作者关键词:   ndoped graphene, electrochemical sensor, bisphenol a, endocrine disruptor
  • 出版物名称:   ANALYTICA CHIMICA ACTA
  • ISSN:   0003-2670 EI 1873-4324
  • 通讯作者地址:   Univ Jinan
  • 被引频次:   147
  • DOI:   10.1016/j.aca.2011.10.051
  • 出版年:   2012

▎ 摘  要

Bisphenol A (BPA), which could disrupt endocrine system and cause cancer, has been considered as an endocrine disruptor. Therefore, it is very important and necessary to develop a sensitive and selective method for detection of BPA. Herein, nitrogen-doped graphene sheets (N-GS) and chitosan (CS) were used to prepare electrochemical BPA sensor. Compared with graphene, N-GS has favorable electron transfer ability and electrocatalytic property, which could enhance the response signal towards BPA. CS also exhibits excellent film forming ability and improves the electrochemical behavior of N-GS modified electrode. The sensor exhibits a sensitive response to BPA in the range of 1.0 x 10(-8)-1.3 x 10(-6) mol L-1 with a low detection limit of 5.0 x 10(-9) mol L-1 under the optimal conditions. Finally, this proposed sensor was successfully employed to determine BRA in water samples with satisfactory results. (C) 2011 Elsevier B.V. All rights reserved.