• 文献标题:   Graphene oxide (GO)-catalyzed chemoselective thioacetalization of aldehydes under solvent-free conditions
  • 文献类型:   Article
  • 作  者:   ROY B, SENGUPTA D, BASU B
  • 作者关键词:   aldehyde, chemoselectivity, dithioacetal, graphene oxide, thiol
  • 出版物名称:   TETRAHEDRON LETTERS
  • ISSN:   0040-4039
  • 通讯作者地址:   N Bengal Univ
  • 被引频次:   23
  • DOI:   10.1016/j.tetlet.2014.10.043
  • 出版年:   2014

▎ 摘  要

An efficient method for the synthesis of open chain, cyclic, and unsymmetrical dithioacetals from aryl/hetero-aryl/aliphatic aldehydes is described. The reaction is performed using graphene oxide (GO) as the catalyst under solvent-free and aerobic conditions. High chemoselectivity is observed in the reaction as aryl/alkyl ketones do not give thioketals under the condition. (C) 2014 Elsevier Ltd. All rights reserved.