• 文献标题:   Reduced Graphene-Oxide-Encapsulated MoS2/Carbon Nanofiber Composite Electrode for High-Performance Na-Ion Batteries
  • 文献类型:   Article
  • 作  者:   CHO SH, KIM JH, KIM IG, PARK JH, JUNG JW, KIM HS, KIM ID
  • 作者关键词:   molybdenum sulfide, carbon nanofiber, reduced graphene oxide, anode, sodiumion batterie
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   7
  • DOI:   10.3390/nano11102691
  • 出版年:   2021

▎ 摘  要

Sodium-ion batteries (SIBs) have been increasingly studied due to sodium (Na) being an inexpensive ionic resource (Na) and their battery chemistry being similar to that of current lithium-ion batteries (LIBs). However, SIBs have faced substantial challenges in developing high-performance anode materials that can reversibly store Na+ in the host structure. To address these challenges, molybdenum sulfide (MoS2)-based active materials have been considered as promising anodes, owing to the two-dimensional layered structure of MoS2 for stably (de)inserting Na+. Nevertheless, intrinsic issues of MoS2-such as low electronic conductivity and the loss of active S elements after a conversion reaction-have limited the viability of MoS2 in practical SIBs. Here, we report MoS2 embedded in carbon nanofibers encapsulated with a reduced graphene oxide (MoS2@CNFs@rGO) composite for SIB anodes. The MoS2@CNFs@rGO delivered a high capacity of 345.8 mAh g(-1) at a current density of 100 mA g(-1) for 90 cycles. The CNFs and rGO were synergistically taken into account for providing rapid pathways for electrons and preventing the dissolution of S sources during repetitive conversion reactions. This work offers a new point of view to realize MoS2-based anode materials in practical SIBs.