▎ 摘　　要

Alternative high-performance electrocatalysts for triiodide (I-3(-)) reduction of low-cost dye-sensitized solar cells (DSSCs) are urgently sought after. To address the concerned issues, we report a facile strategy for engineering the nitrogen and phosphorus dual-doped graphene (NPG) via an efficient ball-milling process, followed by a simple thermal annealing approach utilizing melamine (C3H6N6) and triphenylphosphine ((C6H5)(3)P) as the N and P source, respectively. When employed as the counter electrode (CE) in DSSCs, such a metal-free material exhibits excellent electrocatalytic activity towards the I-3(-)/I- redox reaction. Dual-doping of N and P heteroatoms can markedly enhance the photovoltaic performance of DSSCs by a synergistic effect and a high conversion efficiency of 8.57% is achieved, which is superior to Pt CE, and much higher than that of the single-component N- or P-doped graphene electrodes. In addition, the NPG CE also shows an outstanding electrochemical stability. The present results demonstrate that the NPG as a low-cost and high-efficiency electrocatalyst for reduction of I-3(-) will be one of the promising CE materials in DSSCs.