• 文献标题:   Direct growth of graphene films without catalyst on flexible glass substrates by PECVD*
  • 文献类型:   Article
  • 作  者:   MIAO RX, ZHAO CH, WANG SQ, REN W, LI YF, SHU TK, YANG B
  • 作者关键词:   graphene, flexible glas, pecvd, rf power
  • 出版物名称:   CHINESE PHYSICS B
  • ISSN:   1674-1056 EI 2058-3834
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1088/1674-1056/abeeec
  • 出版年:   2021

▎ 摘  要

A hydrogen-plasma-etching-based plasma-enhanced chemical vapor deposition (PECVD) synthesis route without metal catalyst for preparing the graphene films on flexible glass is developed. The quality of the prepared graphene films is evaluated by scanning electron microscopy, x-ray photoelectron spectroscopy, high-resolution transmission electron microscopy, ultraviolet-visible spectroscopy, and electrochemical measurements. In a radio frequency (RF) power range of 50 W-300 W, the graphene growth rate increases with RF power increasing, while the intensity ratio of D- to G-Raman peak (I (D)/I (G)) decreases. When the RF power is higher than 300 W, the I (D)/I (G) rises again. By optimizing experimental parameters of hydrogen plasma etching and RF power, the properties of as-prepared flexible graphene on glass are modulated to be able to achieve the graphene's transparency, good electrical conductivity, and better macroscopic uniformity. Direct growth of graphene film without any metal catalyst on flexible glass can be a promising candidate for applications in flexible transparent optoelectronics.