• 文献标题:   Fabrication of binder-free graphene-SnO2 electrodes by laser introduced conversion of precursors for lithium secondary batteries
  • 文献类型:   Article
  • 作  者:   LU XX, WU GL, XIONG QQ, QIN HY, WANG WB, LUO F
  • 作者关键词:   binderfree, graphene, sno2, lithium battery
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Hangzhou Dianzi Univ
  • 被引频次:   6
  • DOI:   10.1016/j.apsusc.2017.02.151
  • 出版年:   2017

▎ 摘  要

Binder-free graphene-SnO2 electrodes were prepared by laser introduced conversion of precursor (mixture of graphene oxide and stannic oxide sol) coatings on a copper film. The evolution of the microstructure, thermal stability, morphologies and sheet resistance has been studied as a function of laser fluences. It was shown that the conversion of precursors is mainly attributed to the photothermic effect, and a laser fluence of 69.3 J cm(-2) is the best condition for sample preparation. When the as-prepared electrode used as an anode for lithium ion batteries, it has been demonstrated with a high lithium storage capacity and good cycling stability. A high capacity of around 700 mAh g(-1) can be retained after 50 cycles at a current density of 100 mA g(-1), and even after 400 cycles the specific capacity steadied to around 690 mAh g(-1). Such electrodes have a short preparing procedure and good electrochemical performance, so the fabrication method adopted here could be referable for industrial continuous production. (C) 2017 Elsevier B.V. All rights reserved.