• 文献标题:   Sandwich-type ordered mesoporous carbon/graphene nanocomposites derived from ionic liquid
  • 文献类型:   Article
  • 作  者:   KIM HS, KIM YH, ROH KC, KIM KB
  • 作者关键词:   ionic liquidderived carbon, ordered mesoporous carbon/graphene nanocomposite, 2d graphene nanocomposite, supercapacitor
  • 出版物名称:   NANO RESEARCH
  • ISSN:   1998-0124 EI 1998-0000
  • 通讯作者地址:   Yonsei Univ
  • 被引频次:   7
  • DOI:   10.1007/s12274-016-1158-y
  • 出版年:   2016

▎ 摘  要

Sandwich-type ordered mesoporous carbon/graphene nanocomposites were successfully synthesized using 2D ordered mesoporous silica/graphene nanocomposites as the hard template and an ionic liquid as a N-rich carbon source. We used an ionic liquid of 1-(3-cyanopropyl)-3-methylimidazolium dicyanamide containing nitrile groups (-CN) in the cation and anion as a carbon precursor for the preparation of the nanocomposites. Nitriles do not decompose under thermal treatment in an inert gas atmosphere, but leave significant amounts of N-rich carbon materials. The nanocomposites had a large surface area (1,316 m(2)center dot g(-1)), an average pore diameter of 5.9 nm, and high electrical conductivity. The nanocomposite electrode showed a high specific capacitance of 190 F center dot g(-1) at 0.5 A center dot g(-1) in 1 M TEABF(4)/AN electrolyte and a good rate capability between 0 and 2.7 V for supercapacitor (or ultracapacitor) applications.