• 文献标题:   Styrene-Based Elastomer Composites with Functionalized Graphene Oxide and Silica Nanofiber Fillers: Mechanical and Thermal Conductivity Properties
  • 文献类型:   Article
  • 作  者:   PARK J, SHARMA J, MONAGHAN KW, MEYER HM, CULLEN DA, ROSSY AM, KEUM JK, WOOD DL, POLIZOS G
  • 作者关键词:   sbr composite, sbs composite, graphene oxide, silica nanofiber, mechanical propertie, thermal conductivity
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:   Oak Ridge Natl Lab
  • 被引频次:   0
  • DOI:   10.3390/nano10091682
  • 出版年:   2020

▎ 摘  要

The mechanical and thermal conductivity properties of two composite elastomers were studied. Styrene-butadiene rubber (SBR) filled with functionalized graphene oxide (GO) and silica nanofibers, and styrene-butadiene-styrene (SBS) block copolymers filled with graphene oxide. For the SBR composites, GO fillers with two different surface functionalities were synthesized (cysteamine and dodecylamine) and dispersed in the SBR using mechanical and liquid mixing techniques. The hydrophilic cysteamine-based GO fillers were dispersed in the SBR by mechanical mixing, whereas the hydrophobic dodecylamine-based GO fillers were dispersed in the SBR by liquid mixing. Silica nanofibers (SnFs) were fabricated by electrospinning a sol-gel precursor solution. The surface chemistry of the functionalized fillers was studied in detail. The properties of the composites and the synergistic improvements between the GO and SnFs are presented. For the SBS composites, GO fillers were dispersed in the SBS elastomer at several weight percent loadings using liquid mixing. Characterization of the filler material and the composite elastomers was performed using x-ray photoelectron spectroscopy, x-ray diffraction, transmission electron microscopy, scanning electron microscopy, thermogravimetric analysis, dynamic mechanical analysis, tensile testing, nanoindentation, thermal conductivity and abrasion testing.