• 文献标题:   A super-hydrophilic partially reduced graphene oxide membrane with improved stability and antibacterial properties
  • 文献类型:   Article
  • 作  者:   LI QX, HUANG ZH, LIN XL, ZHU YH, BAI XH
  • 作者关键词:   antibacterial, nanofiltration membrane, partially reduced graphene oxide, tea polyphenol
  • 出版物名称:   WATER SCIENCE TECHNOLOGY
  • ISSN:   0273-1223 EI 1996-9732
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.2166/wst.2022.273
  • 出版年:   2022

▎ 摘  要

In order to improve stability and antibacterial property, a novel super-hydrophilic partially reduced graphene oxide membrane was prepared by interfacial polymerization of piperazine and partially reduced graphene oxide as aqueous solution and trimesoyl chloride as organic solution. Fourier transform infrared spectroscopy, scanning electron microscope, and contact angle measurement were conducted to probe the morphology and properties of the membranes. The modified membrane possessed super-hydrophilicity, improved durability and swelling resistance. The optimized membrane had a molecular weight cut off of about 674 Da and possessed a pure water permeability of 49.86 L center dot m(-2)center dot h(-1)center dot MPa-1. The retention order of salts was Na2SO4 > MgSO4 > MgCl2 > Na2CO3 > CaCl2 > NaCl, while the rejection for four kinds of pharmaceuticals followed the order of ibuprofen (92%) > carbamazepine (87%) > amlodipine (80%) > atenolol (76%), indicating that the negatively charged membrane could improve the retention performance by the electrostatic repulsive effect. Moreover, the enhanced antibacterial performance of membrane attributed to the dual effects of the super-hydrophilicity and the tea polyphenols antibacterial material loading, which may alter the charge distribution on and within the membrane, leading to loss of cell viability.