• 文献标题:   Surface modification of silica-graphene nanohybrid as a novel stabilizer for oil-water emulsion
  • 文献类型:   Article
  • 作  者:   TAJIK S, NASERNEJAD B, RASHIDI A
  • 作者关键词:   chemical vapor deposition, nanostructure, functional group, silicagraphene, stabilizer
  • 出版物名称:   KOREAN JOURNAL OF CHEMICAL ENGINEERING
  • ISSN:   0256-1115 EI 1975-7220
  • 通讯作者地址:   Amirkabir Univ Technol
  • 被引频次:   2
  • DOI:   10.1007/s11814-017-0125-y
  • 出版年:   2017

▎ 摘  要

The surface modification of silica-graphene nanohybrid through treatment with a mixture of nitric and sulfuric acid vapors to prepare a novel stabilizer for decalin-water emulsion was investigated. The nanohybrid was prepared through chemical vapor deposition using silica aerogel and acetylene as catalyst and carbon precursor at atmospheric pressure and 600 A degrees C. The physicochemical properties of the modified nanohybrid were characterized by FT-IR, XPS, Raman spectroscopy, and TEM. The surface modification of nanohybrid was at various duration times (24, 48, and 72 hours) to optimize the surface modification conditions. Zeta potential of -39.9 mV revealed that the surface modification of nanohybrid after 72 hours had an excellent stability in aqueous phase due to the presence of exceptional functional groups. The emulsion average droplet size decreased by increasing the nanohybrid concentration. The negative value of the zeta potential showed the proposed nanohybrid can be applied as an appropriate stabilizer for emulsion.