• 文献标题:   Oscillatory behaviour of the surface reduction process of multilayer graphene oxide at room temperature
  • 文献类型:   Article
  • 作  者:   VOYLOV DN, IVANOV IN, BYKOV VI, TSYBENOVA SB, MERKULOV IA, KUROCHKIN SA, HOLT AP, KISLIUK AM, SOKOLOV AP
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Tennessee
  • 被引频次:   4
  • DOI:   10.1039/c6ra14414d
  • 出版年:   2016

▎ 摘  要

We report the observation of oscillatory redox reactions on the surface of multilayer graphene oxide ( GO) films at room temperature. The redox reactions exhibited dampened oscillatory behavior with a period of about 5 days and were found to be dependent on the time elapsed from film deposition. The kinetic behavior observed for the oxidation-reduction reactions and the metastability of the surface functional groups are adequately described by two models involving GO reactions and reactant diffusion.