• 文献标题:   Monodispersed FeCO3 nanorods anchored on reduced graphene oxide as mesoporous composite anode for high-performance lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   XU DH, LIU WJ, ZHANG CC, CAI X, CHEN WY, FANG YP, YU XY
  • 作者关键词:   lithiumion batterie, ferrous carbonate, reduced graphene oxide, anode material, nanocomposite
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   South China Agr Univ
  • 被引频次:   13
  • DOI:   10.1016/j.jpowsour.2017.08.053
  • 出版年:   2017

▎ 摘  要

The development of advanced 1D/2D hierarchical nanocomposites for high-performance lithium-ion batteries is important and promising. Herein, monodispersed FeCO3 nanorods anchored on reduced graphene oxide (RGO) are prepared via a facile and efficient one-pot hydrothermal synthesis. The influence of RGO content on the morphology and electrochemical performances of the mesoporous FeCO3/reduced graphene oxide (FeCO3/RGO) composites are systematically studied. Optimized FeCO3/RGO composite shows good cycling stability. It delivers an initial discharge capacity of 1449 mAh. g(-1) at the current density of 200 mA g(-1) and maintained a capacity of 789 mAh-g(-1) after 80 cycles. A moderate amount of RGO sheets can not only provide more conductive channels to improve the electrode conductivity, but also effectively buffer the large volume variation of FeCO3 during continuous charge/discharge process. The combination of FeCO3 nanorods with RGOs synergistically contribute to enhanced capacity and durability of the composite anode. It demonstrates that RGO anchored-FeCO3 nanorods should be an attractive candidate as anode material for high-performance lithium-ion batteries. (C) 2017 Elsevier B.V. All rights reserved.