• 文献标题:   Graphene induced band gap widening and luminescence quenching in ceria:graphene nanocomposites
  • 文献类型:   Article
  • 作  者:   UDAYABHASKAR R, MANGALARAJA RV, SAHLEVANI SF, PERARASU VT, KARTHIKEYAN B, CONTRERAS D, GRACIAPINILLA MA
  • 作者关键词:   nanoceria, ceria:graphene, blue shift, fcenter, luminescence
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Univ Concepcion
  • 被引频次:   3
  • DOI:   10.1016/j.jallcom.2018.08.226
  • 出版年:   2019

▎ 摘  要

By this report, we discussed about the synthesis and optical properties of pure ceria (nanospheres) and ceria:graphene nanocomposites (nanorice like morphology) which were prepared by using commercial microwave oven as a cost effective and environmental friendly approach. The influence of graphene on the crystallinity, morphology, band gap energy and luminescence of the synthesized samples were deliberately discussed. The obtained average crystallite size, by using Scherrer formula, of the CeO2 nanostructures exhibited a decreasing trend with increasing the graphene loading. The higher graphene loaded ceria nanocomposites clearly depicted the morphology of nanorice like in shape with the diameter and length as similar to 6 and similar to 50 nm, respectively. The presence of graphene and ceria related vibrational modes in FTIR and Raman spectra along with the structural studies supported the successful formation of the nanocomposites. The observed increase in the band gap (blue shift) of nanoceria was discussed. The luminescence related to various F-centers and its quenching in the ceria nanocomposites was discussed. (C) 2018 Elsevier B.V. All rights reserved.