• 文献标题:   Enhancement of Electrochemical Properties by Freeze-dried Graphene Oxide via Glucose-assisted Reduction
  • 文献类型:   Article
  • 作  者:   CHENG JH, CHEN YH, YEH YS, HY S, KUO LY, HWANG BJ
  • 作者关键词:   reduced graphene oxide, glucose, freezedrying, supercapacitor, interspace
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Natl Taiwan Univ Sci Technol
  • 被引频次:   5
  • DOI:   10.1016/j.electacta.2015.12.116
  • 出版年:   2016

▎ 摘  要

The re-stacking of reduced graphene oxide (rGO) is the main reason to decrease its surface area and the capacitance. A method to prevent graphene sheets from re-stacking is developed in this work by combining glucose filler with a drying process. The rGO/C composite is synthesized via a heat-dry (HD) or freeze-drying (FD) process separately and then thermal reduction under 700 degrees C. The rGO/C composites are characterized by XRD, SEM, TEM and FTIR. The interspace of the GO sheets increases as the glucose amount increases for the freeze-drying process and re-stacking could be reduced after thermal reduction. The capacitance is evaluated via the cyclic voltammetry method, which the rGO/C composite with freeze-drying and 1 wt% glucose addition (FD-1%) could deliver the highest capacitance 157.6 Fg(-1) at 5 mV s(-1) scanning rate. This method we developed provides a way to manipulate the interspace of GO sheet and improve the capacitive performance. (C) 2015 Elsevier Ltd. All rights reserved.