• 文献标题:   Carbon-Encapsulated SnO2 Core Shell Nanowires Directly Grown on Reduced Graphene Oxide Sheets for High-Performance Li-Ion Battery Electrodes
  • 文献类型:   Article
  • 作  者:   LEE SH, NOH Y, JO YR, KIM Y, KIM BJ, KIM WB
  • 作者关键词:   carbon shell, direct growth, lithiumion batterie, reduced graphene oxide, tin dioxide
  • 出版物名称:   ENERGY TECHNOLOGY
  • ISSN:   2194-4288 EI 2194-4296
  • 通讯作者地址:   Pohang Univ Sci Technol POSTECH
  • 被引频次:   6
  • DOI:   10.1002/ente.201700804
  • 出版年:   2018

▎ 摘  要

A designed electrode material of carbon-encapsulated tin dioxide core-shell nanowires that are synthesized directly on reduced graphene oxide substrates is reported, and its application as a positive electrode material for lithium-ion battery is shown. Each of the individual tin dioxide nanowires is wrapped with carbon shell layers and grown on a reduced graphene oxide substrate, which gives rise to structural benefits for electrochemical performance of the lithium-ion battery. Such carbon structures allow the electrode materials to withstand the mechanical stress during repeated charge/discharge processes and facilitate the reaction kinetics for the lithiation/delithiation processes. In the electrochemical cell tests, the synergetic effect of the proposed electrode design is explicitly verified by presenting highly enhanced rate capability and cycle durability on full-cell batteries as well as half-cell tests.