• 文献标题:   Direct self-assembly of Fe2O3/reduced graphene oxide nanocomposite for high-performance lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   XIAO LS, SCHROEDER M, KLUGE S, BALDUCCI A, HAGEMANN U, SCHULZAD C, WIGGERS H
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY A
  • ISSN:   2050-7488 EI 2050-7496
  • 通讯作者地址:   Univ Duisburg Essen
  • 被引频次:   39
  • DOI:   10.1039/c5ta02549d
  • 出版年:   2015

▎ 摘  要

In this study, Fe2O3/reduced graphene oxide (rGO) nanocomposites were prepared using a direct selfassembly of oppositely charged Fe2O3 nanoparticles (NPs) and graphene oxide (GO) sheets, followed with a low-temperature hydrothermal reduction process. The characterization of the nanocomposite shows that Fe2O3 NPs with an average diameter of about 9 nm are uniformly distributed on well-exfoliated rGO layers. The nanocomposites show a high iron oxide mass loading of 63%. The electrical conductivity of the composite was significantly enhanced by about 6 orders of magnitude in comparison to pure Fe2O3 NPs. The characterization of the composite as an anode material for lithium-ion batteries (LIBs) demonstrated a strong positive synergistic effect with respect to its electrochemical performance. Fe2O3/rGO exhibited a capacity of 600 mA h g(-1) at a current density of 0.1 A g(-1), and even more than 180 mA h g(-1) at 10 A g(-1) (approx. 17 C), indicating its superior high-rate performance. In addition, it features high efficiency at high rates and very good cyclic stability over a long cycle life of more than 550 cycles.