• 文献标题:   Silver nanorods attached to graphene sheets as anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   HSIEH CT, LIN CY, CHEN YF, LIN JS, TENG H
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223
  • 通讯作者地址:   Yuan Ze Univ
  • 被引频次:   47
  • DOI:   10.1016/j.carbon.2013.06.002
  • 出版年:   2013

▎ 摘  要

We employed a homogenizing method to disperse silver nanorods onto graphene nanosheets (GNs) in liquid phase, forming a three-dimensional Ag/GN framework. The Ag/GN hybrid material was used to investigate Li-ion insertion/extraction properties. A microwave-assisted polyol approach was adopted to synthesize highly crystalline Ag nanorods. The as-prepared Ag/GN hybrid anode shows improved Li-storage capacity, excellent rate capability, and good cycling stability, as compared with the pure GN anode. The hybrid anode offers a reversible capacity of 1015 mA h g(-1) at 0.1 C and a high capacity retention of 64.1% based on the capacity ratio at 5 C-0.1C rates. The enhancement of anode performance can be attributed to an increased electrode conductivity and interlayer distance due to the insertion of metallic Ag nanorods onto a percolated GN network, thus preventing the re-stacking of graphene sheets. (c) 2013 Elsevier Ltd. All rights reserved.