• 文献标题:   Real-Time Observation of Interlayer Vibrations in Bilayer and Few-Layer Graphene
  • 文献类型:   Article
  • 作  者:   BOSCHETTO D, MALARD L, LUI CH, MAK KF, LI ZQ, YAN HG, HEINZ TF
  • 作者关键词:   graphene, ultrafast spectroscopy, coherent phonon dynamic, adlayer substrate interaction
  • 出版物名称:   NANO LETTERS
  • ISSN:   1530-6984 EI 1530-6992
  • 通讯作者地址:   Columbia Univ
  • 被引频次:   34
  • DOI:   10.1021/nl401713h
  • 出版年:   2013

▎ 摘  要

We report real-time observation of the interlayer shearing mode, corresponding; to the lateral oscillation of graphene planes, for bi- and few-layer graphene. Using a femtosecond pump-probe technique, we have followed coherent oscillations of this vibrational mode directly in the time domain. The shearing-mode frequency, as expected for an interlayer mode, exhibits a strong and systematic dependence on the number of layers, varying from 1.32 THz for the bulk limit to 0.85 THz for bilayer graphene. We explored the role of interactions with the external environment on this vibrational mode by comparing the response observed for graphene layers supported by different substrates and suspended in free space. No significant frequency shifts were observed.