• 文献标题:   Preparation of non-covalently functionalized graphene using 9-anthracene carboxylic acid
  • 文献类型:   Article
  • 作  者:   BOSE S, KUILA T, MISHRA AK, KIM NH, LEE JH
  • 作者关键词:  
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Chonbuk Natl Univ
  • 被引频次:   31
  • DOI:   10.1088/0957-4484/22/40/405603
  • 出版年:   2011

▎ 摘  要

A simple way of achieving stable aqueous dispersion of graphene by non-covalent functionalization using 9-anthracene carboxylic acid has been successfully accomplished. Unlike in chemically reduced graphene, the C-sp(2) network of the graphene remains undistorted and therefore of superior quality. The non-covalent functionalization facilitates the exfoliation of graphite layers in a polarity controlled combination of media. A detailed exfoliation mechanism is proposed based on the controlled experiment and is supported by the data from UV-vis spectroscopy, transmission electron microscopy, and x-ray diffraction studies. Formation of monolayer graphene has been confirmed from Raman spectroscopy. The graphene based ultracapacitor shows a high value of specific capacitance (148 F g(-1)).