• 文献标题:   Ho-Ion-Polymer/Graphene Heterojunctions Toward Room-Temperature Ferromagnets
  • 文献类型:   Article
  • 作  者:   XIA WL, LI CJ, ZHANG SX, WANG XL, WANG S, YANG QL, LI W, XIONG CX, HUANG J, WANG Q
  • 作者关键词:   ferromagnetic, graphene, heterojunction, holmium ion polymer
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1002/smll.202300385 EA MAR 2023
  • 出版年:   2023

▎ 摘  要

Organic ferromagnetic materials offer great promise for spintronic devices, carbon-based chips, and quantum communications, but remain as a challenging issue due to their low saturation magnetization and/or unsustainable ferromagnetic properties. To date, magnetic ion polymers have displayed paramagnetism without exception at room-temperature. In this study, it is reported for the first time that, owing to the structural restriction and charge exchange of Ho ion by polymer/graphene pi-pi stacking heterojunctions, holmium ion polymer composites exhibited typical hysteresis lines of ferromagnetic materials at room temperature. The room-temperature ferromagnetic ion polymer composite presented the highest saturation magnetization value of 3.36 emu g(-1) and unprecedented sustainable ferromagnetism, compared to reported room-temperature organic ferromagnetic materials. Accordingly, prepared ferromagnetic composites also achieved impressive wave absorption properties, with a maximum reflection loss of as much as -57.32 dB and a broad absorption bandwidth of 5.05 GHz. These findings may promote the development of room-temperature organic ferromagnetic materials.