• 文献标题:   Cu doped amine functionalized graphene oxide and its scope as catalyst for selective oxidation
  • 文献类型:   Article
  • 作  者:   RANA S, JONNALAGADDA SB
  • 作者关键词:   copper loaded, amine functionalized, graphene oxide, selective oxidation, benzyl alcohol oxidation, functionalized graphene oxide
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Univ KwaZulu Natal
  • 被引频次:   11
  • DOI:   10.1016/j.catcom.2017.07.002
  • 出版年:   2017

▎ 摘  要

We describe the synthesis of Cu doped amine functionalized graphene oxide (Cu@AGO) and its effective application as recyclable heterogeneous catalyst for selective partial oxidation of benzyl alcohols to corresponding benzaldehydes under mild conditions with acetonitrile as solvent. The Cu@AGO was fully characterized by XRD, FT-IR, Raman spectra, XPS, SEM and TEM analysis. FT-IR validated the successful grafting of organic amine with graphene oxide, while TEM confirmed the uniform distribution of metal particles on amine functionalized graphene oxide. The catalyst gave excellent conversion (92%) and selectivity (99%) towards benzaldehyde, with good reusability up to 4 cycles.