• 文献标题:   Enhanced adsorption behavior of amended EDTA-graphene oxide for methylene blue and heavy metal ions
  • 文献类型:   Article
  • 作  者:   KHADIVI SM, EDJLALI L, AKBARZADEH A, SEYYEDI K
  • 作者关键词:   graphene oxide, surface functionalization, dye removal, edta, methylene blue
  • 出版物名称:   INTERNATIONAL JOURNAL OF ENVIRONMENTAL SCIENCE TECHNOLOGY
  • ISSN:   1735-1472 EI 1735-2630
  • 通讯作者地址:   Islamic Azad Univ
  • 被引频次:   2
  • DOI:   10.1007/s13762-019-02286-7
  • 出版年:   2019

▎ 摘  要

Here, edetic acid (EDTA) structure was chemically modified by aspartic acid and lysine (two alpha -amino acids) over covalent functionalization. The obtained modified EDTA (m-EDTA) was used to functionalize graphene oxide (GO) surface for effective removal of dyes from waste waters. The methylene blue dye was adsorbed on the hybrid sorbent through -pi interactions with GO conjugated surface and also electrostatic interactions with multivalent chelating m-EDTA sites. The synthesized hybrid sorbent has been characterized with X-ray powder diffraction, scanning electron microscope, Fourier transform infrared spectroscopy, and ultraviolet-visible spectroscopy. 0.03 g of synthesized hybrid sorbent has been used for treatment of 30 mL of pollutant (1 g/L). The results indicate high removal efficiency was obtained in first 20 min that verify the modification of the GO has a positive effect on removal efficiency.Graphical abstract